Abstract: In order to study the impact of miners’ work stress on near miss events in coal mines, combined with the survey of miners, the paper summed up seven stressors of the miners’ work stress. By analyzing the influence of the miners’ work stress on the coal mine hazard events, the paper proposes the corresponding hypothesis to establish the initial effect of the miners’ working stress on the near miss events in coal mine. SPSS17.0 and AMOS21.0 softwares are used to conduct statistical analysis of the questionnaire and verification of the model. The results show that the positive effect of miners′ work stress on near miss events is obvious in coal mine; work and family conflict, work characteristics, career development and role stress have significant positive effects on miners’ work stress and near miss events in coal mine. Organizational mechanism and style, self-efficacy, interpersonal relationship have significant negative effects on miners’ work stress and near miss events in coal mine. Finally, according to the research results, the corresponding intervention measures are proposed so as to help the coal mine improve the safety management level.