邬灿春, 秦汝祥, 戴广龙, 王洋. 油浸煤自然发火标志气体确定的实验研究[J]. 煤矿安全, 2018, 49(10): 24-29.
    引用本文: 邬灿春, 秦汝祥, 戴广龙, 王洋. 油浸煤自然发火标志气体确定的实验研究[J]. 煤矿安全, 2018, 49(10): 24-29.
    WU Canchun, QIN Ruxiang, DAI Guanglong, WANG Yang. Experimental Study on Mark Gas Determination of Spontaneous Combustion of Oil-immersed Coal[J]. Safety in Coal Mines, 2018, 49(10): 24-29.
    Citation: WU Canchun, QIN Ruxiang, DAI Guanglong, WANG Yang. Experimental Study on Mark Gas Determination of Spontaneous Combustion of Oil-immersed Coal[J]. Safety in Coal Mines, 2018, 49(10): 24-29.

    油浸煤自然发火标志气体确定的实验研究

    Experimental Study on Mark Gas Determination of Spontaneous Combustion of Oil-immersed Coal

    • 摘要: 陕北地区煤层顶板富含原油,煤矿开采过程中顶板原油浸入采空区遗煤。为研究原油浸入对煤自燃特性的影响,进行了原煤及2%、5%和10%等不同含油质量比煤样的程序升温氧化试验,分析了气体产出特征,给出了预报煤自燃的临界温度,确定了煤自燃预测指标。结果表明:测试温度30~190 ℃之间,不同含油比煤样气体产出具有分段特征,原油占据了部分粒间空隙与孔隙,延缓了煤氧反应进程,且含油程度越高,延缓作用越明显,在剧烈氧化阶段后期(150~190 ℃),同一温度下不同含油比煤样气体产量差值大,且随氧化温度升高,氧化差值越来越大。在原油浸入未知情况下,不利于预测煤自燃氧化阶段,为此采用组合比值项指标预测方法,该方法很好地降低了浸油量对煤自燃预报的影响,提高了预测预报的灵敏性与准确性。最终,按含油程度不同,分类进行油浸煤自然发火预报。

       

      Abstract: The coal seam roof is rich in crude oil in northern Shanxi Province. During the mining process, the crude oil in the roof is immersed in residual coal in the gob. In order to analyze the influence of crude oil immersion on spontaneous combustion of coal, the temperature programmed and oxidation tests of raw coal and coal samples with different oil content ratios of 2%, 5% and 10% were carried out. The gas output characteristics were analyzed. The coal spontaneous combustion prediction index is selected, and the critical temperature is determined. The results show that the gas produced by coal samples adding with different oil ratios has the characteristic of sectioning at 30 ℃ to 190 ℃, the crude oil occupies porosity, retards the progress of coal-oxygen reaction, and the higher the oil ratio, the more obvious delaying effect. In the late stage of vigorous oxidation(150 ℃ to 190 ℃), the gas production difference of different oil ratios is much larger at the same temperature. With the increase of oxidation temperature, the oxidation difference becomes larger and larger. In the case of crude oil in unknown, it is not conducive to predict spontaneous combustion of coal oxidation stage, therefore, the combined ratio index forecasting method is adopted, the method can reduce the influence of oil immersion on coal spontaneous combustion prediction and improve the sensitivity and accuracy of prediction. Finally, according to the degree of oil content, the prediction of spontaneous combustion of oil-immersed coal is classified.

       

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