刘先新, 吉晓波. 贫氧环境下褐煤升温氧化特性的实验研究[J]. 煤矿安全, 2021, 52(5): 36-41.
    引用本文: 刘先新, 吉晓波. 贫氧环境下褐煤升温氧化特性的实验研究[J]. 煤矿安全, 2021, 52(5): 36-41.
    LIU Xianxin, JI Xiaobo. Experimental study on temperature-increasing oxidation characteristics of lignite in oxygen-poor environment[J]. Safety in Coal Mines, 2021, 52(5): 36-41.
    Citation: LIU Xianxin, JI Xiaobo. Experimental study on temperature-increasing oxidation characteristics of lignite in oxygen-poor environment[J]. Safety in Coal Mines, 2021, 52(5): 36-41.

    贫氧环境下褐煤升温氧化特性的实验研究

    Experimental study on temperature-increasing oxidation characteristics of lignite in oxygen-poor environment

    • 摘要: 为了研究贫氧环境下褐煤的升温氧化特性,以内蒙古宝日希勒第一煤矿1#煤层煤样为研究对象,利用热重-气相色谱联用技术在不同氧气体积分数下对煤样进行升温氧化实验,得出贫氧环境下褐煤的热特性曲线(TG、DTG、DSC),同时采用Coats-Redfern动力学方程计算了煤样热解阶段和燃烧阶段的活化能。结果表明:贫氧环境对煤升温燃烧的各个阶段产生不同程度的影响;随着氧气体积分数的降低,特征温度T3、T4和Tmax逐渐增大;吸氧增重阶段增重量和放热量逐渐减小;热解和燃烧阶段的失重量逐渐减少,放热量逐渐降低,活化能呈减小趋势;CO和CO2峰值温度向高温区域偏移且峰值浓度降低。

       

      Abstract: In order to study the temperature-increasing oxidation characteristics of lignite under oxygen-poor conditions, the coal sample of 1# coal seam of Baorixile 1# coal mine was taken as the research object, and the coal samples were subjected to temperature-oxidation under different oxygen concentrations by thermogravimetry-gas chromatography. The thermal characteristic curves(TG, DTG, DSC) of lignite under oxygen-depleted conditions were obtained through experiments. At the same time, the activation energy of pyrolysis stage and combustion stage of coal samples were calculated by Coats-Redfern kinetic equation. The results show that the oxygen-depleted environment has different degrees of influence on each stage of coal combustion. As the oxygen concentration decreases, the characteristic temperatures T3, T4, and Tmax gradually increase; the weight gain and heat release gradually decrease during the oxygen absorption and weight increase phase; the weight loss, the heat release and the activation energy of the pyrolysis and combustion phases gradually decrease. The peak temperature of CO and CO2 shifts to the high temperature region and the peak concentration decreases.

       

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