李仲文, 张志强, 陈曦, 邬丛珊. 表面活性剂对无烟煤煤尘的抑尘效果研究[J]. 煤矿安全, 2022, 53(2): 27-32.
    引用本文: 李仲文, 张志强, 陈曦, 邬丛珊. 表面活性剂对无烟煤煤尘的抑尘效果研究[J]. 煤矿安全, 2022, 53(2): 27-32.
    LI Zhongwen, ZHANG Zhiqiang, CHEN Xi, WU Congshan. Study on dust suppression effect of surfactant on anthracite coal dust[J]. Safety in Coal Mines, 2022, 53(2): 27-32.
    Citation: LI Zhongwen, ZHANG Zhiqiang, CHEN Xi, WU Congshan. Study on dust suppression effect of surfactant on anthracite coal dust[J]. Safety in Coal Mines, 2022, 53(2): 27-32.

    表面活性剂对无烟煤煤尘的抑尘效果研究

    Study on dust suppression effect of surfactant on anthracite coal dust

    • 摘要: 研究了脂肪醇聚氧乙烯醚(AEO9)、十二烷基硫酸钠(SDS)和十二烷基三甲基溴化胺(DTAB)3种表面活性剂溶液对晋城无烟煤呼吸性粉尘的抑尘效果。在临界胶束质量分数(CMC)下,利用悬滴法和座滴法分别测定了表面活性剂溶液的动态表面张力和在无烟煤表面的动态接触角;利用分子动力学模拟研究了表面活性剂与无烟煤的吸附强度、胶束的稳定性以及单分子在水中的扩散系数。实验结果表明:AEO9溶液对煤尘的降尘效果最好,SDS次之,DTAB最差;在临界胶束质量分数(CMC)以上,悬滴平衡态表面张力值依次是AEO99(865.3 ms)9溶液在无烟煤表面的动态接触角下降最快。模拟结果表明:AEO9与无烟煤表面的相互作用强度最强,DTAB次之,SDS最弱;虽然AEO9在水中的扩散系数小于SDS和DTAB,但AEO9在溶液中形成的胶束最容易解离;这应该是AEO9溶液抑尘效果较好的微观原因。

       

      Abstract: In this paper, the dust inhibition effect of fatty alcohol polyoxyethylene ether(AEO9), sodium dodecyl sulfate(SDS) and dodecyl trimethylamine bromide(DTAB) on respirable dust from Jincheng anthracite was studied. The dynamic surface tension of the surfactant solution and the dynamic contact angle on the surface of anthracite were measured by hanging drop method and pedicle drop method at CMC concentration; the adsorption strength of the surfactant and anthracite, the stability of the micelle and the diffusion coefficient of the single molecule in water were studied by molecular dynamics simulation. Experimental results show that AEO9 solution has the best dust reduction effect on coal dust, followed by SDS and DTAB the worst. Above the critical micelle concentration(CMC), the equilibrium surface tension of the hanging drop is AEO99(865.3 ms)9 solution on the surface of anthracite drops the fastest. The simulation results show that the interaction strength between AEO9 and the surface of anthracite is the strongest, followed by DTAB, and SDS is the weakest. Although the diffusion coefficient of AEO9 in water is smaller than that of SDS and DTAB, but the micelles formed by AEO9 in solution are most easily dissociated. It is the reason why the AEO9 solution has better dust suppression effect.

       

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