阜康矿区煤层气井产出水水文地球化学特征及意义

    Hydrogeochemical characteristics and significance of produced water from coalbed methane wells in Fukang Mining Area

    • 摘要: 为探究阜康矿区煤层产出水的水文地球化学特征、火烧区滞水层和煤层水的补给关系以及水化学演化模式,采集了该矿区3个井区的煤层气井产出水样,开展了离子浓度、矿化度、氢氧同位素以及溶解无机碳同位素的测试及展布特征分析,并采用对比、分析方法,结合构造特征和水文地质条件进行了分析。研究表明:3个井区的煤层气井产出水以Na−HCO3和Na−HCO3·Cl型水为主,矿化度较高;火烧区滞水层是C井区煤层水的重要补给来源,从火烧区滞水层处向阜康向斜轴部呈现出补给区向滞流区过渡的特征;3个井区的氢氧同位素均落在大气降水线附近,且C井区的氢氧同位素表现出明显的18O漂移特征,主要因为地下水在火烧区滞水层发生了18O漂移;C井区煤层气井产出水的δ13CDIC的值最大,表明微生物作用强烈,存在次生生物气;3个井区的溶解无机碳同位素与硫酸根含量呈负相关关系,且与产气量的相关性明显,可作为判识次生生物煤层气富集有利区的参考因素。

       

      Abstract: In order to explore the hydrogeochemical characteristics of coal seam water produced in Fukang Mining Area, the recharge relationship between stagnant aquifer and coal seam water in the fire area and the water chemical evolution model, this study collected water samples from coalbed methane wells in three well areas of the mining area, and carried out the test and spread characteristics of ion concentration, mineralization, hydrogen-oxygen isotope and dissolved inorganic carbon isotope, and analyzed by comparative and analysis methods, combined with structural characteristics and hydrogeological conditions. Research shows that the produced water of coalbed methane wells in the three well areas is mainly Na-HCO3 and Na-HCO3·Cl type water with high salinity; the stagnant water layer in the burning area is an important source of coal seam water supply in well C, and the transition from the stagnant water layer in the burning area to Fukang inclined axis is characteristic of the recharge area to the stagnant water area; the hydrogen-oxygen isotopes in the three well areas all fell near the atmospheric precipitation line, and the hydrogen-oxygen isotopes in the C well area showed obvious 18O drift, which was mainly due to the 18O drift of groundwater in the stagnant water layer in the burning area; the value of δ13CDIC in the produced water of coalbed methane wells in C well area was the largest, indicating that the microbial effect was strong and secondary biogas existed; the dissolved inorganic carbon isotopes in three well areas were negatively correlated with sulfate concentration, and the correlation with gas production was obvious, which could be used as a reference factor to identify the favorable area for secondary biological CBM enrichment.

       

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