不同温度条件对CO2−ECBM的影响研究

    Study on the effect of different temperature conditions on CO2-ECBM

    • 摘要: 为探究温度条件对CO2强化煤层气采收(CO2−ECBM)的影响,基于吸附热力学、渗流力学等理论,构建了考虑非等温吸附效应的CO2−ECBM全耦合模型,系统研究了不同温度条件对CO2−ECBM过程中多物理场动态演变的影响。结果表明:在CO2−ECBM过程中,CH4的解吸和CO2的吸附分别是吸热和放热反应,这导致煤储层温度发生显著变化;随着注入时间的延长,煤储层温度可以分为微微下降、急剧上升、急剧下降和逐渐平稳4个阶段,且注入时间的延长会导致煤储层中的温度异常区域逐渐扩大;与此同时,煤储层渗透率的变化受气体解吸/吸附导致的煤基质收缩/膨胀与热膨胀效应共同影响,二者相互竞争决定煤储层渗透率的最终演变趋势;在CO2尚未渗入的煤储层区域,CH4解吸引发的煤基质收缩效应主导煤储层渗透率演化,注入温度与煤储层渗透率呈正相关关系,而煤储层初始温度则与渗透率呈负相关关系;当CO2与CH4在煤储层交汇后,煤储层渗透率由气体竞争吸附和热膨胀的净效应所主导,注入温度与煤储层渗透率的关系转变为负相关关系,而煤储层初始温度与渗透率的关系则转变为正相关关系;此外,注入温度的升高可有效提升CH4生产效率和CO2存储效率,而煤储层初始温度的升高则会降低CH4生产效率与CO2存储效率。

       

      Abstract: In order to investigate the effect of temperature conditions on CO2-ECBM (CO2-enhanced coalbed methane), this study constructed a fully coupled model of CO2-ECBM considering the non-isothermal adsorption effect based on the theories of adsorption thermodynamics and seepage mechanics, and systematically investigated the effect of different temperature conditions on the dynamic evolution of multi-physical fields in the CO2-ECBM process. The results show that the desorption of CH4 and adsorption of CO2 in the CO2-ECBM process are adsorptive and exothermic reactions, respectively, which will lead to significant changes in the temperature of the coal reservoir. With the extension of injection time, the coal reservoir temperature can be divided into four stages: slight decrease, sharp increase, sharp decrease and gradual stabilization, and the extension of injection time will lead to the gradual expansion of the temperature anomaly region in the coal reservoir. At the same time, the change of coal reservoir permeability is affected by the contraction/expansion of coal matrix due to gas desorption/adsorption and thermal expansion which compete with each other to determine the final evolution of coal reservoir permeability. In the area where CO2 has not yet infiltrated into the coal reservoir, the contraction of the coal matrix due to CH4 desorption dominates the evolution of the permeability of the coal reservoir, and the injection temperature is positively correlated with the permeability of the coal reservoir, while the initial temperature of the coal reservoir is negatively correlated with the permeability. After the intersection of CO2 and CH4 in the coal reservoir, the permeability of the coal reservoir is dominated by the net effect of gas competition adsorption and thermal expansion, and the relationship between the injection temperature and the permeability of the coal reservoir changes to a negative correlation, while the relationship between the initial temperature of the coal reservoir and the permeability changes to a positive correlation. In addition, the increase of injection temperature can effectively improve the CH4 production efficiency and CO2 storage efficiency, while the increase of initial temperature of coal reservoir can reduce the CH4 production efficiency and CO2 storage efficiency.

       

    /

    返回文章
    返回