注气压力对CO2置换驱替CH4的影响试验研究

    Experimental study on the influence of injection pressure on CO2 displacement and replacement of CH4

    • 摘要: 注气压力是煤层注气促抽瓦斯的重要技术参数。为研究CO2置换驱替CH4过程中CO2注气压力对CH4产出与CO2储存特性变化的影响,利用自主搭建的CO2置换驱替CH4实验系统,开展不同注气压力下(0.6、0.8、1.0 MPa)CO2置换驱替CH4实验,定量分析置换驱替过程中出口CH4流量、CO2储存量、孔隙压力、置换体积比、CH4产出率和CO2储存率等参数随注气压力的变化规律。结果表明:在低压范围内(0.6~1.0 MPa),提高CO2注气压力有助于产出更多的CH4及储存更多CO2,注气压力越大,CO2储存量、置换体积比、CH4产出率和CO2储存率越大,CO2突破时间及达到新的吸附饱和状态所需时间越短;当注气压力为0.6、0.8、1.0 MPa时,实验结束时CO2储存量分别为16.48、16.74、19.91 cm3/g,CH4产出率分别为76.98%、78.94%、81.27%,CO2储存率分别为72.76%、87.80%、86.11%,置换体积比分别为2.98、2.90、3.33,突破时间分别为76.00、74.00、64.83 min;当注气压力由0.6 MPa增至1.0 MPa时,CO2储存量和CH4产出率分别提高了20.81%和4.29%;出口CH4流量随注气时间增加呈现缓慢增加、逐渐减小并趋于稳定的变化规律,孔隙压力呈现逐渐增大并趋于稳定的变化规律(逐渐趋近CO2注气压力)。整个注气驱替过程可分为3个阶段,主导控制效应分别为CO2驱赶游离CH4、CH4自解吸和置换驱替及CO2稀释载携CH4。在技术现场应用过程中,应针对每个阶段的具体特性合理调整优化相关工艺参数,使注CO2驱替CH4及CO2地质储存技术更高效。

       

      Abstract: Gas injection pressure is an important technical parameter of gas injection for gas drainage in coal seam. In order to study the effects of CO2 gas injection pressure on the changes of CH4 production and CO2 storage characteristics in the process of CO2 displacing CH4, the self-built CO2 displacing CH4 experimental system was used to carry out the CO2 displacing CH4 with different CO2 gas injection pressures (0.6 MPa, 0.8 MPa and 1.0 MPa). The changes of CH4 flow rate, CO2 storage, pore pressure, replacement volume ratio, CH4 production rate and CO2 storage rate with gas injection pressure during displacement were quantitatively analyzed. The experimental results show that in the low pressure range of 0.6-1.0 MPa tested, increasing the CO2 injection pressure is conducive to producing more CH4 and storing more CO2. The greater the gas injection pressure, the greater the CO2 storage capacity, replacement volume ratio, CH4 production rate and CO2 storage rate, and the shorter the CO2 breakthrough time and the time required to reach the new adsorption saturation state. When the gas injection pressure was 0.6 MPa, 0.8 MPa, and 1.0 MPa, the CO2 storage capacity at the end of the experiment was 16.48 cm3/g, 16.74 cm3/g, and 19.91 cm3/g, respectively, and the production rate of CH4 was 76.98%, 78.94%, and 81.27%. The CO2 storage rate was 72.76%, 87.80%, and 86.11%, and the replacement volume ratio was 2.98, 2.90, and 3.33, respectively, and the breakthrough time was 76.00 min, 74.00 min, and 64.83 min, respectively. When the gas injection pressure increased from 0.6 MPa to 1.0 MPa, the CO2 storage capacity and CH4 production rate increased by 20.81% and 4.29%, respectively. With the increase of gas injection time, the flow rate of CH4 at the outlet increases slowly, decreases gradually and tends to be stable, and the pore pressure increases gradually and tends to be stable (gradually approaching the CO2 gas injection pressure). The whole gas injection displacement process can be divided into three stages, and the dominant control effects are CO2 driving away free CH4, CH4 self-desorption and displacement, and CO2 dilution carrying CH4. In the field application process, relevant process parameters should be reasonably adjusted and optimized according to the specific characteristics of each stage, so as to make the technology of CO2 injection for CH4 displacement and CO2 geological storage is more efficient.

       

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