凝胶结壳型煤尘抑制剂的制备与性能研究

    Preparation and properties of gel crust-type coal dust suppressant

    • 摘要: 为解决煤矿生产、运输及堆储过程中煤尘污染问题,降低煤矿工人尘肺职业病发病率,基于天然高分子改性理念,以黄原胶(XG)和羟丙基甲基纤维素(HPMC)为复合底物,在引发剂与交联剂作用下,引入N−羟甲基丙烯酰胺(NAM)分子链进行接枝改性制得凝胶成膜组分,与表面活性剂十二烷基磺酸钠(SDDS)和保水剂聚乙烯吡咯烷酮(PVP)复配,制备了一种具有凝胶网络结构的结壳型煤尘抑制剂。利用傅里叶变换红外光谱(FTIR)、X射线光电子能谱(XPS)和扫描电子显微镜(SEM)表征手段研究了接枝过程和抑尘机理,并通过黏度测试、溶胀能力测试和抑尘性能试验验证其性能优势。结果表明:抑尘剂中凝胶网络结构显著提升了材料的黏结性与溶胀性,可有效黏结煤粉并在煤尘表面形成致密固结层,从而提升抑尘效果;保水性能测试中,抑尘剂处理的煤样在45 ℃下蒸发5 h后保水率大于50%;抗风蚀性能测试中,抑尘剂处理的煤样在15 m/s风速下抗风蚀效率较传统洒水处理的煤样提高79.5%,且固结层形貌保持完好;固结层耐候性测试中,抑尘剂处理煤样经过7次冻融循环试验后,固结层硬度仅下降12%,且固结层无明显裂纹。研究表明,制备的凝胶抑尘剂可显著抑制煤尘扩散,为矿区环境保护和煤矿工人职业健康防护提供了新策略。

       

      Abstract: In order to solve the coal dust pollution problem in the process of coal mine production, transportation and storage and reduce the incidence of pneumoconiosis among coal workers, based on the concept of natural polymer modification, a gel film-forming component was synthesized through graft copolymerization of N-hydroxymethyl acrylamide (NAM) chains onto a composite substrate of xanthan gum (XG) and hydroxypropyl methylcellulose (HPMC) under the action of initiators and cross-linking agents, this modified component was subsequently compounded with the surfactant sodium dodecyl sulfonate (SDDS) and the humectant polyvinylpyrrolidone (PVP) to fabricate a crust-type coal dust suppressant featuring a gel network structure. The grafting process and dust suppression mechanism were investigated using Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS) elemental analysis, and scanning electron microscopy (SEM). The performance advantages were validated through viscosity tests, swelling capacity tests, and dust suppression performance tests. The results demonstrated that the gel network structure within the dust suppressant significantly enhanced the cohesive properties and swelling capacity of the material. This improvement effectively bonded coal particles and formed a dense consolidated layer on the coal dust surface, thereby enhancing the dust suppression efficiency; in the water retention test, the dust suppressant-treated coal sample exhibited a water retention rate exceeding 50% after evaporation at 45 ℃ for 5 h; in the consolidation layer weather resistance test, the dust suppressant-treated coal samples exhibited a 79.5% enhancement in wind erosion resistance efficiency compared to traditionally water-sprayed samples under a wind speed of 15 m/s, while the consolidated layer morphology remained intact. In the wind erosion resistance test, the dust suppressant-treated coal samples subjected to 7 freeze-thaw cycles between −20 ℃ and 50 ℃ exhibited only a 12% reduction in consolidated layer hardness, with no visible cracks observed in the consolidated layer. The study shows that the developed gel-based dust suppressant significantly suppressed coal dust dispersion, thereby offering a novel approach for environmental protection in mining areas and occupational health safeguarding for coal miners.

       

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