煤体CO2与CH4竞争吸附特征研究

    Research on competitive adsorption characteristics of CO2 and CH4 in coal

    • 摘要: 深入了解煤层中CO2和CH4的竞争吸附特性对实现CO2稳定封存和CH4高效回采具有重要意义。基于CO2与CH4竞争吸附试验系统,研究了不同条件下煤体CO2与CH4的竞争吸附特征。结果表明:单组分吸附时,CO2吸附速率快于CH4,煤体更快达到饱和吸附状态;在较大浓度梯度作用下,CH4可逆向驱替出已吸附的CO2,但驱替耗时大于CO2驱替CH4的过程;竞争吸附时,CO2在煤体内的竞争吸附能力强于CH4;以30 ℃为界,温度过低或过高会降低气体吸附速率;注气流速的增加使得气体总压强增大,促使竞争吸附过程缩短,当气体成分中优势吸附性气体占比低于弱势吸附性气体时,其竞争吸附过程会受到抑制,反之则会促进该过程更快完成。

       

      Abstract: Deep understanding of the competitive adsorption characteristics of CO2 and CH4 in coal seams is of great significance for achieving stable CO2 storage and efficient CH4 recovery. This study studies the competitive adsorption characteristics of CO2 and CH4 in coal under different conditions based on the CO2 and CH4 competitive adsorption experimental system. The results showed that the adsorption rate of CO2 was faster than that of CH4 in single-component adsorption, and the coal body reached the saturation adsorption state more quickly. Under the effect of larger concentration gradient, CH4 can reverse displace the adsorbed CO2, but the displacing time is longer than that of CO2 displacing CH4. The competitive adsorption capacity of CO2 in the coal is stronger than that of CH4. Based on the boundary of 30 ℃, too low or too high temperature will reduce the gas adsorption rate and prolong the competitive adsorption process of CO2 and CH4 in the coal. The increase of gas injection flow rate makes the total gas pressure increase, which leads to the shortening of the competitive adsorption process. When the proportion of dominant adsorption gas in the gas composition is lower than that of weak adsorption gas, the competitive adsorption process will be inhibited, and vice versa, it will promote the process to be completed faster.

       

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